In this Research Spotlight episode hosted by our Editorial Board member Kathleen Cheasty, Jayanta Dey joins us to share his work on the photochemical oximesulfonylation of alkenes.
Key reference:
Angew. Chem. Int. Ed. 2023, 62, e202312384.
https://doi.org/10.1002/anie.202312384
Additional references (in order of appearance):
Molecules 2021, 26(22), 7051.
Eur. J. Org. Chem., 2020, 1379-1392; Eur. J. Org. Chem., 2017, 2056-2071.
Chem. Eur. J. 2021, 27, 4412; Green Chem., 2017,19, 2530; Org. Lett. 2022, 24, 29, 5276; Org. Lett. 2022, 24, 8047−8051.
Curr. Org. Chem. 2016, 21, 249−271; RSC Adv. 2015, 5, 79361−79384.
J. Am. Chem. Soc. 2009, 131, 13214; ACS Catal. 2016, 6, 6465−6472; J. Am. Chem. Soc. 1996, 118, 5138.
Angew. Chem., Int. Ed. 2016, 55, 9695−9699; Org. Lett. 2021, 23, 8353−8358.
Oxident free photocatalytic oxime group transfer. See our work Org. Lett. 2022, 24, 8047−8051.
Photochemical N−O bond cleavage of oximes, see Perkin Trans. 2, 2000, 1868-1875.
For pioneering work on these acyl anion equivalents, see J. Am. Chem. Soc. 1971, 93, 5286-5287.
For all kind of bifunctional reagent, see Nat Rev Chem 5, 301–321 (2021).