Photochemical Oximesulfonylation of Alkenes with Jayanta Dey

Опубликовано: 27 Декабрь 2024
на канале: Synthesis Workshop Videos
1,663
51

In this Research Spotlight episode hosted by our Editorial Board member Kathleen Cheasty, Jayanta Dey joins us to share his work on the photochemical oximesulfonylation of alkenes.

Key reference:
Angew. Chem. Int. Ed. 2023, 62, e202312384.
https://doi.org/10.1002/anie.202312384

Additional references (in order of appearance):
Molecules 2021, 26(22), 7051.
Eur. J. Org. Chem., 2020, 1379-1392; Eur. J. Org. Chem., 2017, 2056-2071.
Chem. Eur. J. 2021, 27, 4412; Green Chem., 2017,19, 2530; Org. Lett. 2022, 24, 29, 5276; Org. Lett. 2022, 24, 8047−8051.
Curr. Org. Chem. 2016, 21, 249−271; RSC Adv. 2015, 5, 79361−79384.
J. Am. Chem. Soc. 2009, 131, 13214; ACS Catal. 2016, 6, 6465−6472; J. Am. Chem. Soc. 1996, 118, 5138.
Angew. Chem., Int. Ed. 2016, 55, 9695−9699; Org. Lett. 2021, 23, 8353−8358.
Oxident free photocatalytic oxime group transfer. See our work Org. Lett. 2022, 24, 8047−8051.
Photochemical N−O bond cleavage of oximes, see Perkin Trans. 2, 2000, 1868-1875.
For pioneering work on these acyl anion equivalents, see J. Am. Chem. Soc. 1971, 93, 5286-5287.
For all kind of bifunctional reagent, see Nat Rev Chem 5, 301–321 (2021).