Juanfran's penalty gave Atletico Madrid a dramatic shoot-out victory over PSV after the sides drew 0-0 in their second leg of their round of 16 Champions League tie.
Following a goalless first leg in Holland last month, the initial 90 minutes at the Vicente Calderon also passed without either keeper being beaten.
Although the hosts dominated for much of the match, the closest they came was when Fernando Torres' effort was touched on to the post and ultimately spot-kicks were required